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Zinc can be coated on iron to produce galvanized iron but the reverse is not possible. It is because

zinc has higher negative electrode potential than iron
zinc is lighter than iron
zinc has lower melting point than iron
zinc has lower negative electrode potential than iron
Explanation:

E0
Zn+2 / Zn
= – 0.76 V

E0
Fe+2 / Fe
= – 0.76 V

Zn has higher negative SRP (Standard reduction potential) so it works as anode and protect iron to make iron as cathode.

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