Considering the basic strength of amines in aqueous solution, which one has the smallest pKb value?

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Considering the basic strength of amines in aqueous solution, which one has the smallest pK_b value?

CH₃NH₂

(CH₃)₃N

C₆H₅NH₂

(CH₃)₂NH

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Hoffmann Bromamide Degradation reaction is shown by _____.

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